Dual accounts/email addresses

I have a personal email address and a work related email address on my eM Client. Both receive emails but only the work related one is capable of sending. How do I get the choice to send from either?

When you “Compose” , Reply or Forward an email, click the “Down Arrow” on the right of your default email address and choose which email address you want to send from.

(eM Client for Windows example below).

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Thank you.

It would appear that I have an issue with my SMTP which causes me to receive via IMAP and not send!

What error message do you get when trying to send, and whats your smtp server setting for the account that won’t send.